PUBLICATIONS
Publications lists by year
(134) K. Ackermann, C. Heubach, O. Schiemann*, B.E. Bode*
“Pulse Dipolar Electron Paramagnetic Resonance Spectroscopy Distance Measurements at Low Nanomolar Concentrations: The CuII-Trityl Case”
Phys. Chem. Lett. 2024, 15, 1455–1461.
(133) K. Kopp, L. Westhofen, T. Hett, M.F. Schwering-Sohnrey, M. Mayländer, S. Richert, O. Schiemann*
“Synthesis and dark state EPR properties of PDI−trityl dyads and triads”
Chem. Eur. J. 2024, 30, e202303.
(132) D. Abdullin, P. Rauh Corro, T. Hett, O. Schiemann*
“PDSFit: PDS data analysis in the presence of orientation selectivity, g-anisotropy, and exchange coupling”
Magn. Reson. Chem. 2024, 62, 37–60.
(131) C.A. Heubach, Z. Hasanbasri, D. Abdullin, A. Reuter, B. Korzekwa, S. Saxena, O. Schiemann*
"Differentiating between Label and Protein Conformers in Pulsed Dipolar EPR Spectroscopy with the dHis-Cu2+(NTA) Motif"
Chem. Eur. J. 2023, 29, e202302541.
(130) M. Mayländer, K. Kopp, O. Nolden, M. Franz, P. Thielert, A.V. Jentzsch, P. Gilch, O. Schiemann, S. Richert∗
"PDI–trityl dyads as photogenerated molecular spin qubit candidates"
Chem. Sci. 2023, 14, 10727–10735.
(129) A. Lisouskaya*, O. Schiemann, I. Carmichael
"Unveiling the Mechanism of Photodamage to Sphingolipid Molecules via Laser Flash Photolysis and EPR"
Photochem. Photobiol. 2023, 99, 1400–1411.
(128) D. Abdullin, T. Hett, N. Fleck, K. Kopp, S. Cassidy, S. Richert, O. Schiemann*
“Magneto-Structural Correlations in a Mixed Porphyrin(Cu2+)/Trityl Spin System: Magnitude, Sign, and Distribution of the Exchange Coupling Constant“
Chem. Eur. J. 2023, 29, e202203148.
(127) D. Abdullin, M. Suchatzki, O. Schiemann*
"Six-pulse RIDME sequence to avoid background artifacts“
Appl. Magn. Reson. 2022, 53, 539–554.
(126) J. Borggräfe, J. Victor, H. Rosenbach, A. Viegas, C.G.W. Gertzen, C. Wuebben, H. Kovacs, D. Riesner, G. Steger, O. Schiemann, H. Gohlke, I. Span, M. Etzkorn*
“Time-resolved structural analysis of an RNA-cleaving DNA catalyst”
Nature 2022, 601,144–149.
(125) M.F. Vicino, C. Wuebben, M. Kerzhner, M. Famulok, O. Schiemann*
“Spin labeling of long RNAs via click reaction and enzymatic ligation”
Meth. Mol. Biol. 2022, 2439, 205–221.
(124) C. Wuebben, O. Schiemann*
“Quantifying the number and affinity of Mn2+ binding sites with EPR spectroscopy”
Meth. Mol. Biol. 2022, 2439, 91–101.
(123) T. Hett, O. Schiemann*
“PELDOR measurements on nitroxide-labelled oligonucleotides”
Meth. Mol. Biol. 2022, 2439, 241–274.
(122) O. Schiemann*, C.A. Heubach, D. Abdullin, K. Ackermann, M. Azarkh, E.G. Bagryanskaya, M. Drescher, B. Endeward, J.H. Freed, L. Galazzo, D. Goldfarb, T. Hett, L.E. Hofer, L.F. Ibáñez, E.J. Hustedt, S. Kucher, I. Kuprov, J.E. Lovett, A. Meyer, S. Ruthstein, S. Saxena, S. Stoll, C.R. Timmel, M. Di Valentin, H.S. Mchaourab*, T.F. Prisner*, B.E. Bode*, E. Bordignon*, M. Bennati*, G. Jeschke*
"Benchmark test and guidelines for DEER/PELDOR experiments on nitroxide-labeled biomolecules”
J. Am. Chem. Soc. 2021, 143, 17875–17890.
(121) D. Nguyen, D. Abdullin, C. A. Heubach, T. Pfaffeneder, A. Nguyen, A. Heine, K. Reuter, F. Diederich, O. Schiemann*, G. Klebe*
"Unraveling a ligand-induced twist of a homodimeric enzyme by pulsed electron–electron double resonance"
Angew. Chem. Int. Ed. 2021, 60, 23419–23426.
(120) T. Hett, T. Zbik, S. Mukherjee, H. Matsuoka, W. Bönigk, D. Klose, C. Rouillon, N. Brenner, S. Peuker, R. Klement, H.-J. Steinhoff, H. Grubmüller, R. Seifert, O. Schiemann*, U. B. Kaupp*
"Spatiotemporal Resolution of Conformational Changes in Biomolecules by Combining Pulsed Electron-Electron Double Resonance Spectroscopy with Microsecond Freeze-Hyperquenching"
J. Am. Chem. Soc. 2021, 143, 6981–6989.
(119) P. Brünker, L. Domenianni, N. Fleck, J. Lindner, O. Schiemann, P. Voehringer*
"Intramolecular O─H···S hydrogen bonding in threefold symmetry. Line broadening dynamics from ultrafast 2DIR-spectroscopy and ab initio calculations“
J. Chem. Phys. 2021, 154, 134305.
(118) M.F. Vicino, T. Hett, O. Schiemann*
"Spin Labeling of RNA Using “Click”-Chemistry for Coarse-Grained Structure Determination via Pulsed Electron-Electron Double Resonance Spectroscopy”
Bio-Protocol 2021, 11, e4004.
(117) O. Schiemann
„Trendbericht: Elektronen-Paramagnetische-Resonanzspektroskopie“
Nachrichten aus der Chemie 2021, 69, 54–62.
(116) N. Fleck, C. Heubach, T. Hett, S. Spicher, S. Grimme, O. Schiemann*
"Ox‐SLIM: Synthesis of and Site‐Specific Labelling with a Highly Hydrophilic Trityl Spin Label”
Chem. Eur. J. 2021, 27, 5292–5297.
(115) O. Nolden, N. Fleck, E.R. Lorenzo, M. R. Wasielewski, O. Schiemann, P. Gilch, S. Richert*
“Excitation energy transfer and exchange‐mediated quartet state formation in porphyrin‐trityl systems”
Chem. Eur. J. 2021, 27, 2683–2691.
(114) A. Lisovskaya*, O. Shadyro, O. Schiemann, I. Carmichael
"OH radical reactions with the hydrophilic component of sphingolipids"
Phys. Chem. Chem. Phys. 2021, 23, 1639–1648.
(113) D. Abdullin, O. Schiemann*
"Localization of Metal Ions in Biomolecules by means of Pulsed Dipolar EPR Spectroscopy"
Dalton Trans. 2021, 50, 808–815.
(112) H. Rosenbach, J. Borggräfe, J. Victor, C. Wuebben, O. Schiemann, W. Hoyer, G. Steger, M. Etzkorn*, I. Span*
"Influence of monovalent metal ions on metal binding and catalytic activity of the 10-23 DNAzyme”
Biol. Chem. 2021, 402, 99–111.
(111) Y. NejatyJarohmy, S.C. Roy, R. Glaum, O. Schiemann*
"Multi-Frequency and Single-Crystal EPR on V4+ in W-Doped β-Vanadyl(V) Phosphate: Hyperfine Coupling- and g-Tensor Values and Orientation“
Appl. Magn. Reson. 2021, 52, 169–175.
Book chapter 10): O. Schiemann „Studying Ribozymes with Electron Paramagnetic Resonance Spectroscopy“ in Ribozymes: Principles, Methods , Applications (Eds.: S. Müller, B. Masquida, W. Winkler). Wiley-VCH, 2021.
Book chapter 9): G. Hagelueken, O. Schiemann „EPR-Spektroskopie an biologischen Systemen“ in Bioanalytik (Eds.: J. Kurrek, J. W. Engels, F. Lottspeich)
Springer, 4. Auflage, 2021.
(110) S. Spicher, D. Abdullin, S. Grimme*, O. Schiemann*
“Modeling of spin-spin distance distributions for nitroxide labeled biomacromolecules”
Phys. Chem. Chem. Phys. 2020, 22, 24282–24290.
(109) K. Kopp, O. Schiemann, N. Fleck*
"Improved, Odorless Access to Benzo[1,2-d;4,5-d’]-bis[1,3]dithioles and Tert-butyl Arylsulfides via C-S Cross Coupling”
Molecules 2020, 25, 3666.
(108) C. Wuebben, M.F. Vicino, M. Mueller, O. Schiemann*
"Do the P1 and P2 hairpins of the Guanidine-II Riboswitch interact?”
Nucleic Acids Res. 2020, 48, 10518–10526.
(107) D. Abdullin*
“AnisoDipFit: Simulation and Fitting of Pulsed EPR Dipolar Spectroscopy Data for Anisotropic Spin Centers”
Appl. Magn. Reson. 2020, 51, 725–748
(106) N. Fleck, C.A. Heubach, T. Hett, F.R. Haege, P.P. Bawol, H. Baltruschat, O. Schiemann*
"SLIM: A short-linked, highly redox-stable trityl label for high-sensitivity in-cell EPR distance measurements“
Angew. Chem. Int. Ed. 2020, 59, 9767–9772.
(105) C. Domnik, F. Eggert, C. Wuebben, L. Bornewasser, G. Hagelueken, O. Schiemann*, S. Kath-Schorr*
“EPR Distance measurements on long non-coding RNAs empowered by genetic alphabet expansion transcription”
Angew. Chem. Int. Ed. 2020, 59, 7891–7896.
(104) D. Abdullin*, O. Schiemann*
"Pulsed Dipolar EPR Spectroscopy and Metal Ions: Methodology and Biological Applications"
ChemPlusChem 2020, 85, 353–372.
(103) C. Wuebben, S. Blume, D. Abdullin, D. Brajtenbach, F. Haege, S. Kath-Schorr, O. Schiemann*
"Site-Directed Spin Labeling of RNA with a gem-Diethylisoindoline Spin Label: PELDOR, Relaxation, and Reduction Stability"
Molecules 2019, 24, 4482.
(102) D. Abdullin, P. Brehm, N. Fleck, S. Spicher, S. Grimme, O. Schiemann*
“Pulsed EPR Dipolar Spectroscopy on Spin Pairs with one Highly Anisotropic Spin Center: The Low‐Spin FeIII Case”
Chem. Eur. J. 2019, 25, 14388-14398.
(101) J.J. Jassoy, C.A. Heubach, T. Hett, F. Bernhard, F.R. Haege, G. Hagelueken, O. Schiemann*
“Site Selective and Efficient Spin Labeling of Proteins with a Maleimide-Functionalized Trityl Radical for Pulsed Dipolar EPR Spectroscopy”
Molecules 2019, 24, 2735.
(100) M. F. Peter, A. Tuukkanen, C. A. Heubach, A. Selsam, F. G. Duthie, D. Svergun, O. Schiemann, G. Hagelueken*
"Studying conformational changes of the Yersinia type-III-secretion effector YopO in solution by integrative structural biology"
Structure 2019, 27, 1-11.
(99) D. Abdullin, H. Matsuoka, M. Yulikov, N. Fleck, C. Klein, S. Spicher, G. Hagelueken, S. Grimme, A. Lützen, O. Schiemann*
"Pulsed EPR Dipolar Spectroscopy under the Breakdown of the High-Field Approximation: The High-Spin Iron(III) Case"
Chem. Eur. J. 2019, 25, 8820-8828.
(98) Fleck, N.; Hett, T.; Brode, J.; Meyer, A.; Richert, S.; Schiemann, O.*
"C-C Cross Coupling reactions of Trityl Radicals: Spin Density Delocalization, Exchange Coupling, and a Spin Label"
J. Org. Chem. 2019, 84, 3293-3303.
(97) D. Abdullin, N. Fleck, C. Klein, P. Brehm, S. Spicher, A. Lützen, S. Grimme, O. Schiemann*
"Synthesis of μ2-oxo-bridged iron(III) tetraphenylporphyrin-spacer-nitroxide dimers and their structural and dynamics characterization by using EPR and MD simulations"
Chem. Eur. J. 2019, 25, 2586-2596.
(96) C. Domnick, G. Hagelueken, O. Schiemann, S. Kath-Schorr*
"Posttranscriptional spin labeling of RNA by tetrazine-based cycloaddition"
Org. Biomol. Chem. 2019, 17, 1805-1808.
(95) Engelhard, D.M.; Meyer, A.; Berndhäuser, A.; Schiemann, O.*; Clever, G.H.*
"Di-Copper(II) DNA G-Quadruplexes as EPR Distance Rulers"
Chem. Commun. 2018, 54, 7455-7458.
(94) Kerzhner, M.; Matsuoka, H.; Wuebben, C.; Famulok, M.; Schiemann, O*
"High-yield spin labeling of long RNAs for EPR Spectroscopy"
Biochemistry 2018, 57, 2923-2931.
(93) A. Meyer, J. J. Jassoy, S. Spicher, A. Berndhäuser, O. Schiemann*
"Performance of Pulsed Dipolar Spectroscopy Methods in measuring distances in trityl based bi- and triradicals: exchange coupling, pseudosecular coupling and multi-spin effects"
Phys. Chem. Chem. Phys. 2018, 20, 13858-13869.
(92) Wittich, K.; NejatyJahromy, Y.; Abdullin, D.; Schiemann, O.; Karpov, A.; Dobner, K.; Rosowski, F.; Glaum, R.*
"Silver Vanadyl(IV) ortho‐Pyrophosphate: Synthesis, Crystal Structure, and Characterization of the (V≡O)2+ Group"
Z. Anorg. Allg. Chem. 2018, 644, 424-429.
(91) N. Fleck, G. Schnakenburg, A. C. Filippou, O. Schiemann*
"Tris[2,2,6,6-tetramethyl-8-(trimethylsilyl)benzo[1,2-d;4,5-d']bis(1,3-dithiol)-4-yl]methanol diethyl ether monosolvate"
Acta Cryst. E 2018, E74, 539-542.
(90) J.J. Jassoy, S. Spicher, C. Wübben, A. Meyer, O. Schiemann*
"Synthesis of Nanometer Sized Bis- and Tris-trityl Model Compounds with Different Extent of Spin-Spin Coupling"
Molecules 2018, 23, 682.
popular science 3): Jassoy, J.J.; Schiemann, O. "Intracellular Ruler: EPR-Based Structural Elucidation of Biomolecules"
GIT 2018, 22, 16-19.
Book chapter 8): Schiemann, O.; Hagelüken, G. "EPR Spectroscopy" in Bioanalytics (Eds: Lottspeich, Engels), Wiley-VCH, 2018.
(89) Matsuoka, H.*; Retegan, M.; Schmitt, L.; Höger, S.; Neese, F.; Schiemann, O.
"Time-Resolved EPR and Theoretical Investigations of Metal-Free Room-Temperature Triplet Emitters"
J. Am. Chem. Soc. 2017, 139, 12968-12975.
(88) Bountra, K; Hagelueken, G.; Choudhury; H.G.; Corradi, V.; ElOmari, K.; Wagner, A.; Mathavan, I.; Zirah, S.; Tieleman, D.P.; Schiemann, O.; Rebuffat, S.; Beis, K.*
"Structural basis for antibacterial peptide self-immunity by the bacterial ABC transporter McjD"
EMBO Journal 2017, 36, 3062-3079.
(87) Heurich, T.; Qu, Z.-W.; Schnakenburg, G.; NejatyJahromy, Y.; Schiemann, O.; Grimme, S.; Streubel, R.*
"Chemistry of Thermally Generated Transient Phosphanoxyl Complexes"
Organometallics 2017, 36, 2877-2883.
(86) Yin, D.M.; Hannam, J.S.; Schmitz, A.; Schiemann, O.; Hagelueken, G.*; Famulok, M.*
"Studying the conformation of a receptor tyrosine kinase in solution by inhibitor-based spin labeling"
Angew. Chem. Int. Ed. 2017, 129, 8537-8541.
(85) Jassoy, J.J.; Berndhäuser, A.; Duthie, F.; Kühn, S.P.; Hagelueken, G.; Schiemann, O.*
"Versatile Trityl Spin Labels for Nanometer Distance Measurements on Biomolecules in vitro and within cells"
Angew. Chem. Int. Ed. 2017, 56, 177-181.
popular science 2): Jassoy, J.J.; Schiemann, O. "Intrazelluläres Lineal: EPR-basierte Strukturaufklärung"
GIT 2017, 5, 14-17.
popular science 1): Schiemann, O. "Biomolecular Structure Determination in Cells"
Pan European Networks: Science & Technology 2017, 22, 184-185.
(84) Ratzke, W.; Schmitt, L.; Matsuoka, H.; Bannwarth, C.; Retegan, M.; Bange, S.; Klemm, P.; Neese, F.; Grimme, S.*; Schiemann, O.*; Lupton, J.*; Höger, S.*
"Effect of Conjugation Pathway in Metal-free Room-temperature Dual Singlet-triplet OLED Emitters"
J. Phys. Chem. Lett. 2016, 7, 4802-4808.
(83) Kerzhner, M.; Abdullin, D.; Wiecek, J.; Matsuoka, H.; Hagelueken, G.; Schiemann, O.*; Famulok, M.*
"Post-synthetic Spin-Labeling of RNA via Click Chemistry for PELDOR Measurements"
Chem. Eur. J. 2016, 22, 12113-12121.
(82) Heurich, T.; Qu,Z.-W.; Nozinovic, S.; Schnakenburg, G.; Matsuoka, H.; Grimme, S.*; Schiemann, O.*; Streubel, R.*
"Synthesis and rearrangement of P-nitroxyl substituted PIII and PV phosphanes: A combined experimental and theoretical case study"
Chem. Eur. J. 2016, 22, 10102-10110.
(81) Gölz, J.P.; NejatyJahromy, Y.; Bauer, M.; Muhammad, A.; Schnakenburg, G.; Grimme, S.; Schiemann, O.; Menche, D.*
"Design, Synthesis, EPR-studies and Conformational Bias of Novel Spin-Labeled DCC-Analogs for the Highly Regioselective Labeling of Aliphatic and Aromatic Carboxylic Acids"
Chem. Eur. J. 2016, 22, 9591-9598.
(80) Arz, M.; Schnakenburg, G.; Meyer, A.; Schiemann, O.; Filippou, A.*
"The Si2H Radical supported by two N-Heterocyclic Carbenes"
Chem. Sci. 2016, 7, 4973-4979.
(79) Hagelueken, G.*; Hofmann, J.; Schubert, E.; Duthie, F.G.; Florin, N.; Konrad, L.; Imhof, D.; Morgner, N.; Schiemann, O.
"Studies on the crystal- and solution structure of FeoB from Escherichia coli BL21 using X-ray crystallography, PELDOR spectroscopy and mass spectrometry"
Biophys. J. 2016, 110, 2642-2650.
(78) Meyer, A.; Schiemann, O.*
"PELDOR and RIDME measurements on a high-spin manganese(II) bisnitroxide model complex"
J. Phys. Chem. A 2016, 120, 3463-3472.
(77) D. Schwarz G. Henriques, K. Zimmer, S. Klare, A. Meyer, E. Rojo-Wiechel, M. Bauer, R. Sure, S. Grimme, O. Schiemann,* R. A. Flowers II,* A. Gansäuer*
"Highly active Titanocene-Catalysis for Epoxide Hydrosilylation: Synthesis, Theory, Kinetics, EPR Spectroscopy"
Angew. Chem. Int. Ed. 2016, 55, 7671-7675.
(76) Brewitz, H. H.; Goradia, N.; Schubert, E.; Galler, K.; Kühl, T.; Syllwasschy, B.; Popp, J.; Neugebauer, U.; Hagelueken, G.; Schiemann, O.; Ohlenschläger, O.*; Imhof, D.*
"Heme Interacts with Histidine- and Tyrosine-Based Protein Motifs and Inhibits Enzymatic Activity of Chloramphenicol Acetyltransferase from E. coli"
Biochim. Biophys. Acta General Subjects 2016, 1860, 1343-1353.
(75) Abdullin, D.; Hagelueken, G.; Schiemann, O.*
"Determination of nitroxide spin label conformations via PELDOR and X-ray crystallography"
Phys. Chem. Chem. Phys. 2016, 18, 10428-10437.
(74) Meyer, A.; Abdullin, D.; Schnakenburg, G.; Schiemann, O.*
"Single and Double Nitroxide Labeled Bis(terpyridine)copper(II): Influence of Orientation Selectivity and Multispin Effects on PELDOR and RIDME"
Phys. Chem. Chem. Phys. 2016, 18, 9262-9271.
(73) Matsuoka, H.*; Mizutani, S.; Watanabe, C.; Yamauchi, S.
"High-frequency EPR studies on polymer chain morphology in dip-coated films of polymer-fullerene bulk-heterojunctions"
Bull. Chem. Soc. Jpn., 2016, 89, 378-384.
(72) Schubert, E.; Hett, T.; Schiemann, O.*; NejatyJahromy, Y.
"EPR studies on the kinetics of the α-hydroxyethyl radical generated by Fenton-like chemistry"
J. Magn. Reson. 2016, 265, 10-15.
(71) Constantinescu, A. D.; Petrovic-Stojanovska, B.; Schiemann, O.; Naismith, J.; White, M. F.*
"Taking a molecular motor for a spin: helicase mechanism studied by spin labeling and PELDOR"
Nucleic Acids Res. 2016, 44, 954-968.
Book chapter 7): Matsuoka, H.; Schiemann, O.
"Molecular Spins in Biological Systems"
in Biological Magnetic Resonance (Editors Berliner, Takui) 2016, 31, 51-77.
(70) Meyer, A.; Schnakenburg, G.; Schiemann, O.*
"The crystal structure of 4'-((4-(2,2':6',2''-terpyridyl)phenyl)ethynyl)biphen-4-yl-(2,2,5,5-tetramethyl-N-oxyl-pyrroline)-3-formate"
Acta Cryst. E 2015, 71, 1245-1249.
(69) Hagelueken, G.*; Abdullin, D.; Schiemann, O.*
"mtsslSuite: Probing biomolecular conformation by spin-labeling studies"
Meth. Enzym. 2015, 563, 595-621.
(68) Meyer, A.; Schnakenburg, G.; Glaum, R.*; Schiemann, O.*
"(Bis(terpyridine))copper(II) Tetraphenylborate: A Complex Example for the Jahn-Teller Effect"
Inorg. Chem. 2015, 54, 8456-8464.
(67) Abdullin, D.; Duthie, F.; Meyer, A.; Müller, E.S.; Hagelueken, G.; Schiemann, O.*
"Comparison of PELDOR and RIDME for Distance Measurments between Nitroxides an Low-Spin Fe(III) Ions"
J. Phys. Chem. B 2015, 119, 13534-13542.
(66) Wang, T.; Schrempp, M.; Berndhäuser, A.; Schiemann, O.; Menche, O.*
"Efficient and General Aerobic Oxidative Cross-Coupling of THIQs with Organozinc Reagents Catalyzed by CuCl2: Proof of a Radical Intermediate"
Org. Lett. 2015, 17, 3982-3985.
(65) Arz, M.; Straßmann, M.; Meyer, A.; Schnakenburg, G.; Schiemann, O.*; Filippou, A.C.*
"One-Electron Oxidation of a Disilicon(0) Compund: A Combined Experimental and Theoretical Study of NHC-trapped [Si2]+"
Chem. Eur. J. 2015, 21, 12509-12516.
(64) Meyer, A.; Wiecek, J.; Schnakenburg, G.; Schiemann, O.*
"The crystal structure of 4'-(4-((2,2,5,5-Tetramethyl-N-oxyle-3-pyrroline-3-yl)-ethinyl)-phenyl)-2,2':6',2''-terpyridine"
Acta Cryst. E 2015, 71, 870-874.
(63) Hagelueken, G.*; Duthie, F. G.; Florin, N.; Schubert, E.; Schiemann, O.
"Expression, purification and spin labelling of the ferrous iron transporter FeoB from Escherichia coli BL21 for EPR studies"
Protein Expr. Purif. 2015, 114, 30-36.
(62) Schubert, E.; Florin, N.; Duthie, F.; Brewitz, H. H.; Kühl, T.; Imhof, D.; Hagelueken, G.*; Schiemann, O.*
"Spectroscopic Studies on Peptides and Proteins with Cysteine-Containing Heme Regulatory Motifs (HRM)"
J. Inorg. Biochem. 2015, 148, 49-56.
(61) Eich, A.; NejatyJahromy, Y.; Schiemann, O.; Beck, J.*
"Se4CuX, Te4CuX and Cu2Se7X2 (X = GaCl4) - Coordination Compounds of Neutral Infinite Chalcogen Chains"
Inorg. Chem. Commun. 2015, 58, 20-23.
(60) Abdullin, D.; Florin, N.; Hagelueken, G.; Schiemann, O.*
"EPR-Based Approach for the Localization of Paramagnetic Metal Ions in Biomolecules"
Angew. Chem. Int. Ed. 2015, 54, 1827-1831.
(59) Abdullin, D.; Hagelueken, G.; Hunter, R. I.; Smith, G. M.; Schiemann, O.*
"Geometric model-based fitting algorithm for orientation-selective PELDOR data"
Mol. Phys. 2015, 113, 544-560.
(58) NejatyJahromy, Y. *; Schubert, E.
"Demystifying EPR: A Rookie Guide to the Application of Electron Paramagnetic Resonance Spectroscopy on Biomolecules"
Progr. Biol. Sci. 2014, 4, 133-152.
(57) Roy, S. C.; Glaum, R.*; Abdullin, D.; Schiemann, O.; Quang Bac, N.; Lii, K.-H.
"Solid Solution Formation between Vanadium(V) and Tungsten(V) Oxide Phosphate"
Z. Anorg. Allg. Chem. 2014, 640, 1876-1885.
(56) Florin, N.; Schiemann, O.; Hagelueken, G.*
"High-resolution crystal structure of spin labelled (T21R1) azurin from Pseudomonas aeruginosa: a challenging structural benchmark for in silico spin labelling algorithms"
BMC Struct. Biol. 2014, 14, 16.
(55) Ward, R., Pliotas, C., Branigan, E., Hacker, C., Rasmussen, A., Hagelueken, G., Booth, I. R., Miller, S., Lucocq, J., Naismith, J. H.*, Schiemann, O.*
"Probing the Structure of the Mechanosensitive Channel of Small Conductance in Lipid Bilayers with Pulsed Electron-Electron Double Resonance"
Biophys. J. 2014, 106, 834-842.
(54) Ward, R.; Schiemann, O.
“EPR‐based distance measurements in Oligonucleotides”
Struct. Bond. 2014, 152, 249-282.
(53) Kunjir, N. C.; Reginsson, G. W.; Schiemann, O.*; Sigurdsson, S. T.*
"Measurements of short distances between trityl spin labels with CW EPR, DQC and PELDOR"
Phys. Chem. Chem. Phys., 2013, 15, 19673-19685.
(52) Hagelueken*, G.; Abdullin, D.; Ward, R.; Schiemann, O.
"mtsslSuite: In Silico Spin Labelling, Trilateration and Distance-Constrained Rigid Body Docking in PyMOL"
Mol. Phys. 2013, 111, 2757-2766.
(51) Reginsson, G. W.; Shelke, S.; Rouillon, C.; White, M. F.; Sigurdsson, S. T.; Schiemann, O.*
"Protein-Induced Changes in DNA Structure and Dynamics Observed with Non-Covalent Site-Directed Spin-Labelling and PELDOR"
Nucleic Acids. Res. 2013, 41, e11 .
Book chapter 6): Ward, R.A; Schiemann, O.
"Interspin Distance Determination by EPR"
in Encyclopedia of Biophysics (Editors Roberts E., Gordon, C.K.) 2013, 1116-1123.
Book chapter 5): Reginsson, G.W.; Schiemann, O. "Spin Labeling of DNA and RNA"
in Encyclopedia of Biophysics (Editors Roberts E., Gordon, C.K.) 2013, 2429-2431.
(50) Reginsson, G. W.; Kunjir, N. C.; Sigurdsson, S. T.*; Schiemann, O.*
"Trityl Radicals: Spin Labels for Nanometer-Distance Measurements"
Chem. Eur. J. 2012, 18, 13580-4.
(49) Pliotas, C.; Ward, R.; Branigan, E.; Rasmussen, A.; Hagelueken, G.; Huang, H.; Black, S. S.; Booth, I. R.*; Schiemann, O.*; Naismith, J. H.*
"Conformational State of the MscS mechanosensitive Channel in solution revealed by PELDOR Spectroscopy"
Proc. Natl. Acad. Sci. USA 2012, 109, E2675-E2682.
(48) El Mkami, H.*; Mohideen, I. M.H.; Pal, C.; MacKinnlay, A.; Schiemann, O.; Morris, R. E.
"EPR and magnetic studies of a novel copper metal orgainc framework (STAM-1)"
Chem. Phys. Lett. 2012, 544, 17-21.
(47) Reginsson, G. W.; Hunter, R. I.; Cruickshank, P. A. S.; Bolton, D. R.; Sigurdsson, S. T.; Smith, G. M.*; Schiemann, O.*
"W-Band PELDOR with 1 kW Microwave Power: Molecular Geometry, Flexibility and Exchange Coupling"
J. Magn. Reson. 2012, 216, 175-182.
(46) Hagelüken, G.*; Ward, R.; Naimsith, J. H.; Schiemann, O.
"MtsslWizard: In silico Spin-Labelling and Generation of Distance Distributions in PyMOL"
Appl. Magn. Reson. 2012, 42, 377-391.
Book chapter 4): Schiemann, O. "EPR Spektroskopie an Biologischen Systemen
"
in Bioanalytik (Editors: Lottspeich, F.; Engels, J. W.; Lay, S. Z.) 3rd revised Edition, Elsevier/Spektrum Akademischer Verlag 2012, 441-460.
(45) Marko, A., Margraf, D., Cekan, P., Schiemann, O., Sigurdsson, S. T. & Prisner, T. F.*
“Conformational Flexibility of DNA”
J. Am. Chem. Soc. 2011, 133, 13375-13379.
(44) Edwards, T. E.*, Cekan, P., Reginsson, G. W., Shelke, S. A., Ferre D'Amare, A. R., Schiemann, O., Sigurdsson, S.*
"Crystal Structure of a DNA Containing the Planar, Phenoxazine-Derived Bi-functional Spectroscopic Probe Ç”
Nucleic Acids Res. 2010, 39, 4419-4426.
(43) Reginsson, G. W., Schiemann, O.*
“Pulsed Electron-Electron Double Resonance on Biomacromolecules: Beyond Nanometer Distance Measurements”
Biochem. J. 2011, 434, 353-363.
(42) Reginsson, G. W. & Schiemann, O.*
“Studying Biomolecular Complexes with Pulsed Electron-Electron Double Resonance Spectroscopy”
Biochem. Soc. Trans.
2011, 39, 128-139.
(41) Marko, A.; Margraf, D.; Cekan, P.; Sigurdsson, S. T.; Schiemann, O.; Prisner, T. F.*
“Analytical method to determine the orientation of rigid spin labels in DNA"
Phys. Rev. E
2010, 81, 021911.
(40) Pal, C., Wheatley, P. S., Mkami, H. E., Keeble, D. J., Morris, R. E., Schiemann, O.*
“EPR on Medically Relevant NO Adsorbed to Zn-LTA”
Appl. Magn. Reson. 2010, 37, 619-627.
(39) Clever, G. H., Reitmeier, S. J., Carell, T., Schiemann, O.*
“Antiferromagnetic Coupling of stacked CuII-Salen Complexes in DNA”
Angew. Chem. Int. Ed. 2010, 49, 4927-4929.
(38) Margraf, D., Cekan, P., Prisner, T., Sigurdsson, S., Schiemann, O.*
“Ferro- and antiferromagnetic exchange coupling constants in PELDOR spectra”
Phys. Chem. Chem. Phys. 2009, 11, 6708-6714.
(37) Schiemann, O.*
“Mapping Global Folds of Oligonucleotides by Pulsed Electron-Electron Double Resonance”
Method. Enzym. 2009, 469, 329-351.
(36) Hagelueken, G., Ingledew, W. J., Huang, H., Petrovic-Stojanovska, B., Whitfield, C., ElMkami, H., Schiemann, O.*, Naismith, J. H.*
“PELDOR Spectroscopy Distance Fingerprinting of the Octameric Outer-Membrane Protein Wza from Escherichia coli”
Angew. Chem. Int. Ed. 2009, 48, 2904-2906.
(35) Bode, B. E., Plackmeyer, J., Bolte, M., Prisner, T. F., Schiemann, O.*
“PELDOR on an Exchange Coupled Nitroxide Copper(II) Spin Pair"
J. Organomet. Chem. 2009, 694, 1172-1179.
(34) Schiemann, O.*, Cekan, P., Margraf, D., Prisner, T. F., Sigurdsson, S. T.*
“Relative Orientation of Rigid Nitroxides by PELDOR: Beyond Distance Measurements in Nucleic Acids”
Angew. Chem. Int. Ed. 2009, 48, 3292-3295.
(33) Bode, B. E., Plackmeyer, J., Prinser, T. F., Schiemann, O.*
“PELDOR measurements on a Nitroxide-Labeled Cu(II) Porphyrin: Orientation Selection, Spin-Density Distribution and Conformational Flexibility”
J. Phys. Chem. A 2008, 112, 5064-5073.
(32) Frolow, O., Endeward, B., Schiemann, O., Prisner, T. F., Engels*, J. W.
“Nitroxide Spin Labeled RNA for long range distance measurements by EPR-PELDOR”
Nucleic Acids Symp. Ser. 2008, 52, 153-154.
(31) Kisseleva, N., Khvorova, A., Westhof, E., Schiemann, O.*, Wolfson, A. D.*
“The different role of high- and low-affinity metal ions in cleavage by a tertiary stabilized cis hammerhead ribozyme from tobacco ringspot virus”
Oligonucleotides 2008, 18, 101-110.
Book chapter 3): Schiemann, O. „EPR“
in Nucleic Acids from A–Z (Editor: Müller, S.), Wiley, 2008.
Book chapter 2): Schiemann, O. „Spin-Labeling“
in Nucleic Acids from A – Z (Editor: Müller, S.) Wiley, Weinheim, 2008.
(30) Schiemann, O.*; Prisner, T. F.*
“Long-range distance determinations in biomacromolecules by EPR spectroscopy”
Quart. Rev. Biophys. 2007, 40, 1-53.
(29) Schiemann, O.*; Piton, N.; Plackmeyer, J.; Bode, B. E.; Prisner, T. F.; Engels, J. W.*
“Spin labeling of oligonucleotides with the nitroxide TPA and use of PELDOR, a pulse EPR method, to measure intramolecular distances”
Nat. Protoc. 2007, 2, 904–923.
(28) D. Margraf, B.E. Bode, A. Marko, O. Schiemann, T.F. Prisner*
“Conformational flexibility of nitroxide biradicals determined by X-band PELDOR experiments”
Mol. Phys. 2007, 105, 2153-2160.
(27) Bode, B.; Margraf, D.; Plackmeyer, J. Dürner, G.; Prisner, T. F.; Schiemann, O.*
“Counting the Monomers in Nanometer-Sized Oligomers”
J. Am. Chem. Soc. 2007, 129, 6736-6745.
(26) Piton, N.; Mu, Y.; Stock, G.; Prisner, T. F.; Schiemann, O.*; Engels, J. W.*
“Base-specific spin labeling of RNA for structure determination”
Nucleic Acids Res. 2007, 35, 3128-3143.
(25) Kisseleva, N.; Kraut, S.; Jäschke, A.*; Schiemann, O.*
“Characterizing multiple metal ion binding sites within a ribozyme by Cadmium-induced EPR silencing”
HFSPJ 2007, 1, 127-136.
(24) Schiemann, O.*; Carmieli, R.; Goldfarb, D.
“W-Band 31P-ENDOR on the High-Affinity Mn2+-Binding Site in the Minimal and Tertiary Stabilized Hammerhead Ribozymes”
Appl. Magn. Reson. 2007, 31, 543-552.
(23) Lerner, H.-W.; Margraf, G.; Kretz, T.; Schiemann, O.; Bats, J. W.; Dürner, G.; de Biani, F. F.; Zanello, P.; Bolte, M.; Wagner, M.*
“Redox Behaviour of Pyrazolyl-Substituted 1,4-Dihydroxyarenes: Formation of the Corresponding Semiquinones, Quinhydrones and Quinones”
Z. Naturforsch. B 2006, 61b, 252-264.
Book chapter 1): Schiemann, O. „EPR“
in Bioanalytik (Editors: Lottspeich, F., Engels, J. W.) Spektrum Akademischer Verlag, Heidelberg, 2nd Edition, 2006, 441- 459.
(22) von Feilitzsch, T.; Härter, P.; Schiemann, O.; Michel-Beyerle, M. E.; Steiner, U. E.; Gilch, P.*
“Magnetic Field and Temperature Dependencies Shed Light on the Recombination Kinetics of a Transition Metal Donor/Acceptor System”
J. Am. Chem. Soc. 2005, 127, 15228-15235.
(21) Piton, N.; Schiemann, O.; Prisner, T. F.; Engels, J. W.*
“Synthesis of Spin-Labeled RNAs for Long Range Distance Measurements by PELDOR”
Nucleos. Nucleot. Nucleic. 2005, 24, 771-775.
(20) Kisseleva, N.; Khvorova, A.; Westhof, E.; Schiemann, O.*
"Binding of Manganese(II) to an Extended Hammerhead Ribozyme as studied by Electron Paramagnetic Resonance Spectroscopy"
RNA 2005, 11, 1-6.
(19) Elschenbroich, C*; Schiemann, O.; Burghaus, O; Harms, K.
“1,2,4,5-Tetra([5]trovacenyl)benzene: an organometallic tetraradical displaying pronounced electro- and magnetocommunication”
Chem. Commun. 2005, 2149-2151.
(18) Schiemann, O.*; Fritscher, J.; Plackmeyer, J.; Elschenbroich, C.
“Trovacenyl-based Organometallic Triradicals: Spinfrustration, Competing Interactions and Redox Splitting”
Appl. Magn. Reson. 2004, 26, 171-182.
(17) Schiemann, O.*; Piton, N.; Mu Y.; Stock, G.; Engels. J. W.; Prisner, T. F.
“A PELDOR-Based Nanometer Distance Ruler for Oligonucleotides”
J. Am. Chem. Soc. 2004, 126, 5722-5729.
(16) Giese, B.; Carl, B.; Carl, T.; Carell, T.; Behrens, C.; Hennecke, U.; Schiemann, O.*; Feresin, E.
“Excess Electron Transport through DNA: A Single Electron Repairs more than One UV-Induced Lesion”
Angew. Chem. Int. Ed. 2004, 43, 1848-1851.
(15) Schiemann, O.*; Feresin, E.; Carl, T.; Giese, B
“4´-Pivaloyl Substituted Thymidine as a Precursor for the Thymyl Radical. An EPR Spectroscopic Study”
ChemPhysChem 2004, 5, 270-274.
(14) Schiemann, O.*; Fritscher, J.; Kisseleva, N.; Sigurdsson, S. T.; Prisner, T. F.
"Structural Investigation of a High-Affinity MnII Binding Site in the Hammerhead Ribozyme by EPR Spectroscopy and DFT Calculations. Effects of Neomycine B on Metal-Ion Binding”
ChemBioChem 2003, 4, 1057-1065.
(13) Beyer, M.; Fritscher, J.; Feresin, E.; Schiemann, O.*
“Synthesis of Novel Aromatic Nitroxides as Potential DNA Intercalators. An EPR Spectroscopical and DFT Computational Study”
J. Org. Chem. 2003, 68, 2209-2215.
(12) Schiemann, O.*; Weber, A.; Edwards, T. E.; Prisner, T. F.; Sigurdsson, S. T.
“Nanometer Distance Measurements on RNA using PELDOR”
J. Am. Chem. Soc. 2003, 125, 3434-3435.
(11) Elschenbroich, C.*; Wolf, M.; Schiemann, O.; Harms, K.; Burghaus, O.; Pebler, J.
“Head-on versus Side-on [5-5] Bitrovacenes Featuring Benzene and Naphthalene Units as Spacers: How π-Stacking Affects Exchange Coupling and Redox Splitting”
Organometallics 2002, 21, 5810-5819.
(10) Fritscher, J.; Beyer, M.; Schiemann, O.*
“Synthesis, Crystal Structure and Magnetic Properties of a Novel Nitroxide Biradical. Theoretical Investigation of the Exchange Mechanisms”
Chem. Phys. Lett. 2002, 364, 393-401.
(9) Weber, A.; Schiemann, O.*; Bode, B.; Prisner, T. F.
“PELDOR at S- and X-Band Frequencies and the Separation of Exchange Coupling from Dipolar Coupling”
J. Magn. Res. 2002, 157, 277-285.
(8) Strube, T.; Schiemann, O.; MacMillan, F.; Prisner, T. F., Engels, J. W.*
“A new facile method for spin-labeling of oligonucleotides”
Nucleos. Nucleot. Nucleic. 2001, 20, 1271-1274.
(7) Braga, D.*; Maini, L.; Grepioni, F.; Elschenbroich, C.; Paganelli, F.; Schiemann, O.
“Novel Organometallic Building Blocks for Crystal Engineering. Synthesis and Structural Characterization of the Dicarboxylic Acid [Cr0(η6-C6H5COOH)2], of Two Polymorphs of its Oxidation Derivative [CrI(η6-C6H5COOH)2]+[PF6]-, and of the Zwitterionic Form [CrI(η6-C6H5COO)(η6-C6H5COOH)]”
Organometallics 2001, 20, 1875-1881.
(6) Wan, C; Fiebig, T.; Schiemann, O.; Barton, J. K.; Zewail, A. H.*
“Femtosecond direct observation of charge transfer between bases in DNA”
Proc. Natl. Acad. Sci. USA, 2000, 97, 14052-14055.
(5) Schiemann, O.; Turro, N. J.; Barton, J. K.*
“EPR Detection of Guanine Radicals in a DNA Duplex under Biological Conditions: Selective Base Oxidation by Ru(phen)2dppz3+ Using the Flash-Quench Technique”
J. Phys. Chem. B 2000, 104, 7214-7220.
(4) Elschenbroich, C.*; Schiemann, O.; Burghaus, O.; Harms, K.; Pebler, J.
“[5-5]Bitrovacene: Synthesis, Structure, and Intermetallic communication”
Organometallics 1999, 18, 3273-3277.
(3) Behrendt, A.; Screttas, C. G.*; Bethell, D.; Schiemann, O.; Steele, B. R.
“Magnetic and electrochemical investigations on anions derived from oligoketones containing fluorenone and benzophenone units. An approach to the design of stable multiradical organic materials”
J. Chem. Soc., Perkin Trans. 2 1998, 2039-2045.
(2) Elschenbroich, C.*; Voss, S.; Schiemann, O.; Lippek, A.; Harms, K.
"n1-Coordination of Phosphinine to Chromium, Molybdenum, and Tungsten”
Organometallics 1998, 17, 4417-4424.
(1) Elschenbroich, C.*; Schiemann, O.; Burghaus, O.; Harms, K.
“Exchange Interaction Mediated by O-H-O Hydrogen Bonds: Synthesis, Structure, and EPR Study of the Paramagnetic Organometallic Carboxylic Acid (η7-C7H7)V(η5-C5H4COOH)"
J. Am. Chem. Soc. 1997, 119, 7452-7457.